Publication detail

Raman analysis of chemisorbed tribofilm for metal-on-polyethylene hip joint prostheses

RUFAQUA, R. VRBKA, M. HEMZAL, D. CHOUDHURY, D. REBENDA, D. KŘUPKA, I. HARTL, M.

English title

Raman analysis of chemisorbed tribofilm for metal-on-polyethylene hip joint prostheses

Type

journal article in Scopus

Language

en

Original abstract

The biochemical reaction during the formation of lubricant film the in case of a cobalt-chromium ball on an ultrahigh-molecular weight polyethylene cup was studied. Three types of model synovial fluids and hyaluronic acid (HA) at physiologic concentrations were used in the experiment. The coefficient of friction was measured using a pendulum hip simulator, and Raman spectroscopy was used to perceive chemical reactions between the synovial fluid and implant material. Raman spectra evidenced that the three model fluids and HA chemisorbed onto the cobalt-chromium surface. An α-helix structure of the model fluid components was detected on the surface of the prosthesis.

English abstract

The biochemical reaction during the formation of lubricant film the in case of a cobalt-chromium ball on an ultrahigh-molecular weight polyethylene cup was studied. Three types of model synovial fluids and hyaluronic acid (HA) at physiologic concentrations were used in the experiment. The coefficient of friction was measured using a pendulum hip simulator, and Raman spectroscopy was used to perceive chemical reactions between the synovial fluid and implant material. Raman spectra evidenced that the three model fluids and HA chemisorbed onto the cobalt-chromium surface. An α-helix structure of the model fluid components was detected on the surface of the prosthesis.

Keywords in English

synovial fluid; film formation; Raman spectroscopy; bio-tribology; tribo-chemistry

Released

25.05.2021

Publisher

The Institution of Engineering and Technology

Location

Stevenage

ISSN

2405-4518

Volume

7

Number

1

Pages from–to

1–11

Pages count

11

BIBTEX


@article{BUT172283,
  author="Risha {Rufaqua} and Martin {Vrbka} and Dušan {Hemzal} and Dipankar {Choudhury} and David {Rebenda} and Ivan {Křupka} and Martin {Hartl},
  title="Raman analysis of chemisorbed tribofilm for metal-on-polyethylene hip joint prostheses",
  year="2021",
  volume="7",
  number="1",
  month="May",
  pages="1--11",
  publisher="The Institution of Engineering and Technology",
  address="Stevenage",
  issn="2405-4518"
}